Voggenthaler, et al., v. Maryland Square, LLC, et al.,
Filing
1081
ORDER re #1047 Proposed Plan Pursuant to Permanent Injunction. Signed by Judge Robert C. Jones on 3/19/15. (Copies have been distributed pursuant to the NEF - TR)
Case 2:08-cv-01618-RCJ-GWF Document 1047 Filed 07/18/14 Page 1 of 4
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CATHERINE CORTEZ MASTO
Attorney General
WAYNE KLOMP
Deputy Attorney General
Nevada State Bar No. 10109
Tele: (775) 850-4101
100 North Carson Street
Carson City, Nevada 89701
Tele: (775) 684-1217
FAX: (775) 684-1103
Attorneys for Nevada Division
of Environmental Protection
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UNITED STATES DISTRICT COURT
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DISTRICT OF NEVADA
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PETER J. VOGGENTHALER, at al.,
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Plaintiffs,
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v.
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MARYLAND SQUARE, LLC, et al.,
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Defendants,
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AND RELATED CROSS CLAIMS AND THIRD)
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PARTY CLAIMS
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STATE OF NEVADA, DEPARTMENT OF
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CONSERVATION AND NATURAL
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RESOURCES, et al.,
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Plaintiffs,
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v.
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MARYLAND SQUARE SHOPPING CENTER, )
et al.,
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Defendants
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AND RELATED THIRD PARTY CLAIMS
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Case No. 2:08-cv-01618-RCJ-GWF
(consolidated with 3:09-cv-00231-RCJGWF)
SUBMISSION OF PROPOSED PLAN
PURSUANT TO PERMANENT
INJUNCTION
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Plaintiff, the Nevada Division of Environmental Protection, Bureau of Corrective
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Actions (“NDEP”), by and through its counsel, Catherine Cortez Masto, Attorney General for
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the State of Nevada, Wayne Klomp, Deputy Attorney General, hereby submit the attached
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Case 2:08-cv-01618-RCJ-GWF Document 1047 Filed 07/18/14 Page 2 of 4
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Proposed Plan to the Court pursuant to the Permanent Injunction Governing the Clean Up of
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Hazardous Substances at and Emanating from Maryland Square Shopping Center (Dkt.
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#592).
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I.
The Proposed Plan and the National Contingency Plan
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The Permanent Injunction anticipates that a Proposed Plan will be prepared by the
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Defendants and submitted to NDEP and the Court after approval of the CAR. However, as
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represented by NDEP counsel at the July 7, 2014 status hearing, NDEP prepared the
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Proposed Plan pursuant to its custom and practice and in compliance with the National
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Contingency Plan (“NCP”), 40 CFR part 300.
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According to the NCP, the lead agency is to prepare Proposed Plan “that briefly
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describes the remedial alternatives analyzed by the lead agency, proposes a preferred
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remedial action alternative, and summarizes the information relied upon to select the
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preferred alternative.” 40 CFR § 300.430(f)(2). Although the preferred remedial alternative is
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identified in the Proposed Plan, no final remedy is selected until after a public comment
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period and public meeting. According to the NCP, NDEP is required to release the Proposed
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Plan to the public for a comment period of not less than 30 days and hold a public meeting.
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Id. at § 300.430(f)(3). NDEP then prepares a summary of the comments, criticisms, and new
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information submitted during the public comment period and a response to each issue. Id. at
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§ 300.430(f)(3)(i)(F). The Proposed Plan is neither a final agency decision nor selection of a
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final remedy. Any significant changes in the preferred remedy are addressed in the Record of
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Decision (“ROD”) or a revised proposed plan followed by a ROD. Id. at § 300.430(f)(3)(ii).
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NDEP has prepared the Proposed Plan in a manner not inconsistent with and in
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accordance with the criteria set forth in the NCP. Pursuant to the Permanent Injunction,
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NDEP submits the Proposed Plan, attached hereto as Exhibit 1, to the Court. Upon approval
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by the Court of the Corrective Action Report (“CAR”) (submitted in Dkt. #1046), NDEP will
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release the Proposed Plan to the public and initiate the public comment period and public
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meeting procedures contemplated by the NCP and Code of Federal Regulations. See 40
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CFR § 300.430(f)(3). At the conclusion of the public comment period, NDEP will prepare the
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Case 2:08-cv-01618-RCJ-GWF Document 1047 Filed 07/18/14 Page 3 of 4
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required summary of and response to public comments or revise the proposed plan as
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provided by the NCP.
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The only changes anticipated to the Proposed Plan prior to release to the public are
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the dates highlighted on pages 2, 3, and 19. Currently, the Plan indicates the public comment
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period will run from August 1, 2014 to October 1, 2014. Those dates may change depending
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upon the actual date the Proposed Plan is released to the public.
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DATED this 18th day of July, 2014.
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CATHERINE CORTEZ MASTO
Attorney General
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By:
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/s/ Wayne Klomp
Wayne Klomp
Attorneys for Nevada Division
of Environmental Protection
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ORDER
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IT IS SO ORDERED this 19th day of March, 2015.
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ROBERT C. JONES
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Case 2:08-cv-01618-RCJ-GWF Document 1047 Filed 07/18/14 Page 4 of 4
CERTIFICATE OF SERVICE
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I, Linda Deming, certify that I am an employee of the Office of the Attorney General,
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State of Nevada, and that on this 18th day of July, 2014, I electronically filed the foregoing,
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SUBMISSION OF PROPOSED PLAN PURSUANT TO PERMANENT INJUNCTION, via
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electronic filing to which the Clerk of the Court will notify the following via their internet and/or
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email address:
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/s/ Linda Deming
Linda Deming, Legal Secretary II
an employee of the Office of the
Nevada Attorney General
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Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 1 of 20
Nevada Division of Environmental Protection
Proposed Plan for Cleanup of Groundwater
Maryland Square PCE Site
Las Vegas, Nevada
The Nevada Division of Environmental Protection (NDEP) is the lead agency providing regulatory oversight for the
investigation and cleanup of contaminated sites in Nevada. As part of the process for cleanup of large-scale sites, the
NDEP prepares a Proposed Plan, consistent with the process followed by the U.S. Environmental Protection Agency
(USEPA). This Proposed Plan describes the proposed cleanup of contaminated groundwater to protect people and the
environment at the Maryland Square PCE Site, located in Clark County, Nevada (Figure 1).
This Proposed Plan presents the Preferred Alternative for cleanup of contaminated groundwater at the Maryland
Square PCE Site and summarizes other alternatives that were evaluated. The Proposed Plan also provides information on
public participation, including a public meeting. Members of the public are encouraged to attend the public meeting and
to review and comment on the remedy proposed for the cleanup of groundwater at the Maryland Square PCE Site.
PROPOSED PLAN AT A GLANCE
Statement of the Problem
A former dry cleaner in the former Maryland Square Shopping Center at 3661 S. Maryland Parkway operated from 1969
to 2000. Tetrachloroethylene (PCE) spilled inside the dry cleaners contaminated the soil and migrated into the shallow
groundwater. After reaching groundwater, the PCE was transported offsite, forming what is known as a “plume” in the
groundwater. This PCE plume extends approximately 6,000 feet downgradient from the source area at the former dry
cleaner, and runs beneath the Boulevard Mall and a portion of the residential neighborhood east of the Mall (Figure 1).
Figure 1. Location Map and Estimated Contours of the Maryland Square PCE Plume
Proposed Plan for the Maryland Square PCE Site
Page 1 of 20
Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 2 of 20
PCE and Vapor Intrusion
Figure 2. The vapor intrusion process
PCE belongs to a group of chemicals known as “volatile
organic compounds” (VOCs). As the PCE volatilizes
(evaporates) from groundwater, the vapors fill pore
spaces in the subsurface soil. PCE vapors in the soil can
then migrate upward and into buildings. This process is
known as “vapor intrusion” (Figure 2)
The health concern at the Maryland Square PCE Site is
the migration of PCE vapors from the contaminated
groundwater and up into homes overlying the PCE
plume. These vapors can accumulate in the homes,
where residents are exposed to PCE by inhalation of the
contaminated indoor air. Testing of indoor air in the
homes began in 2007, and mitigation systems have
been offered to homeowners in cases where the
concentrations of PCE exceed the NDEP’s interim-action
level for residential indoor air. Mitigation systems
provide a short-term solution by intercepting the vapors
before they can enter the home; however, the longterm solution is cleanup of the PCE-contaminated
groundwater.
Proposed Remedy for Cleanup of Groundwater
The NDEP proposes to prevent continued migration of the PCE-contaminated groundwater and to clean up the
contamination using several types of remediation technologies. To prevent further migration of PCE into the
neighborhood, the NDEP proposes construction of a groundwater extraction and treatment system (also known as a
“pump and treat” system) for hydraulic containment of the PCE plume upgradient of the residential neighborhood. The
main mass of PCE remains beneath Maryland Parkway and a portion of the western parking lot at the Boulevard Mall. To
destroy this mass, other cleanup technologies, such as “air sparging and vapor extraction” (AS/VE) and “in situ chemical
oxidation” (ISCO) with re-circulation wells, are proposed for treatment of PCE-contaminated groundwater near
Maryland Parkway. Treatment of the PCE mass west of the Boulevard Mall should decrease the length of time required
for extraction and treatment of groundwater on the east side of the mall property.
Your Comments on the Plan
The NDEP is providing this Proposed Plan, along with a Proposed Plan Fact Sheet, for public review and comment, and
to encourage public involvement. You may provide comments on this Proposed Plan verbally during the public meeting
on _______________, or in writing any time during the 60-day review period, from August 1, 2014 to October 1, 2014.
Although this is not a “Superfund” site, the NDEP is issuing this Proposed Plan as part of its community involvement
program, consistent with requirements of the December 2010 Permanent Injunction issued by the US District Court and
Section 117(a) of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA, commonly
known as Superfund). This Plan is also consistent with Sections 300.430(f) and 300.435(c) of the National Oil and
Hazardous Substances Pollution Contingency Plan and Nevada Administrative Code 445A.22755, which describe holding
a meeting to obtain public input on a proposed cleanup.
This Proposed Plan summarizes information that can be found in greater detail in the case file and Administrative
Record for the Site. The Administrative Record is available in hard copy in the Carson City office of the NDEP and on-line
at: http://ndep.nv.gov/pce/maryland_square.htm
Proposed Plan for the Maryland Square PCE Site
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Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 3 of 20
What is PCE? The contaminant of concern is perchloroethylene, also known as tetracholoroethylene, tetrachloroethene,
perchloroethene, “perc”, or PCE. It is a colorless, nonflammable liquid that does not occur naturally. PCE is a solvent/degreaser used
by dry cleaners to clean fabrics. PCE is also found in some common consumer products, such as glues and spot cleaners.
Public Comment Period
The public comment period runs for 60 days, from August 1, 2014 to October 1, 2014.
Community Meeting
A public meeting will be held on_______ at___________________________________________________________.
The purpose of this meeting is to give the community the opportunity to ask questions and provide comment regarding
the proposed cleanup program. In addition to the public meeting, the public is invited to send their comments via
letters, faxes, and e-mails to the NDEP.
Regulatory Authority
This Proposed Plan was developed in accordance with Nevada Revised Statute 445A and in a manner consistent with
Federal requirements under the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA or
“Superfund”) and the National Contingency Plan by the USEPA.
Contents of the Proposed Plan
I. Site Background
II. History of Site Investigations
III. Scope and Role of Response Action
IV. Summary of Site Risks
V. Remedial Action Objectives
VI. Summary of Remedial Alternatives
VII. Evaluation of Remedial Alternatives
VIII. Preferred Alternative
IX. Community Participation
I.
Glossary of Some Technical Terms
AS/VE means “air sparge and vapor extraction”
CERCLA means “Superfund”
In situ means “in place”
ISCO is “in situ chemical oxidation,” and involves injection of oxidant solutions
into the ground to oxidize (and, thereby, destroy) contaminants
µg/L means “micrograms per liter” (also taken as “parts per billion” [ppb])
µg/m3 means “micrograms per cubic meter” and is a measure of the
concentration of a chemical vapor in air
ROD means “Record of Decision” which documents the selected remedy
USEPA means the “United States Environmental Protection Agency”
VOC means “volatile organic compound”
SITE BACKGROUND
Site Location and Description
The Maryland Square PCE Site includes contaminated soil and groundwater at the site of the former dry cleaners, as well
as an offsite plume of PCE-contaminated groundwater. The dry-cleaning solvent, PCE, is also known as perc,
perchloroethylene, tetrachloroethene or perchloroethene. The source of the PCE contamination was the former Al
Phillips the Cleaner, which was located in the former Maryland Square Shopping Center at 3661 S. Maryland Parkway,
Las Vegas, Nevada. The former shopping center was located on the northwest corner of Maryland Parkway and East
Twain Avenue. This parcel (APN 162-15-602-004) lies across the street from the Boulevard Mall, Clark County, Nevada.
The dry cleaner operated at the Maryland Square site from 1969 through 2000. The exact dates of all spills are not
known; however, at least one major spill in 1982 estimated at 100 gallons of PCE and some minor spills have been
described by former workers at the former dry cleaners. The shopping center was demolished in mid-2006. Following
cleanup of the source area by the excavation and removal of PCE-contaminated soils in the fall of 2011, the property
was re-graded and is currently an empty dirt lot.
Site Geology and Hydrogeology
The site is located in the Las Vegas Valley in southern Nevada. The Las Vegas Valley currently receives an average annual
precipitation of only 4.16 inches. Shallow, non-potable groundwater is generally encountered at a depth of 12 to 25 feet
across the length of the Maryland Square PCE plume. This shallow groundwater is of poor quality and is not used as a
source of drinking water. The shallow groundwater in the area flows in an easterly direction, transporting the PCE
eastward to form a cigar-shaped plume of contaminated groundwater.
Proposed Plan for the Maryland Square PCE Site
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Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 4 of 20
The Valley is filled with sediments eroded from the mountains surrounding the valley. The layers of sediments filling the
basin were deposited on broad alluvial fans. Shallow groundwater flows through these layered sediments. Aquifer tests
performed on the Mall property indicated that that the average rate of groundwater flow ranges from 2.1 to 4.2 ft/day.
These tests also indicated that vertical permeability is nearly 100 times lower than the horizontal permeability at the
site, which means that the contaminated groundwater flows horizontally more easily than vertically.
Chemistry and Behavior of PCE: The high density and low viscosity of PCE allow it to readily migrate through unsealed concrete, as
noted in a guidance document issued by the Colorado Department of Public Health and Environment (CDPHE) for remediation of dry
cleaner sites. “The chemical properties of PCE are such that in liquid form it can readily migrate through unsealed concrete floors and
concrete or asphalt parking lots. Thus, even if spills or leaks of the liquid PCE appear to be “captured or contained” by a hard surface,
the chemical is actually moving into, and rather quickly through, the hard floor or pavement and entering the environment. The same
properties that allow PCE to migrate through concrete floors also allow PCE to migrate rapidly through soil and rock once it is in the
natural environment” (Dry Cleaner Remediation Guidance Document, CDPHE 2006).
Chemistry of Shallow Groundwater
The contaminant plume contains PCE with only trace amounts (generally less than 1%) of the degradation (breakdown)
products, trichloroethylene (TCE), cis-1,2-dichloroethylene (DCE), and vinyl chloride (VC). Slightly greater percentages of
TCE have been measured in some wells just east of the source area.
Conditions in the shallow groundwater indicate an aerobic (oxygenated) environment, with high concentrations of
sulfate. These conditions do not promote degradation of the PCE. Additionally TCE, DCE and VC have not been detected
in wells at the eastern end of the plume. The small amount of organic matter in the soils (typical of soils in desert
environments), does not significantly slow the migration of the PCE in groundwater. Together, these factors have
allowed the PCE plume to migrate more than a mile offsite, even though the bulk of contaminant mass appears to still
reside near Maryland Parkway, just downgradient from the source area at the former dry cleaners.
Deep Groundwater in the Las Vegas Valley
Municipal sources of drinking water come from pumping of the deep aquifer and from Lake Mead. Wells pumping the
deep aquifer typically withdraw water from depths of hundreds of feet. Drilling on mall property indicated the base of
the PCE plume is only about 80 feet deep. Municipal wells and drinking water are routinely monitored, and there is no
evidence that the PCE has caused widespread contamination of the deep aquifer.
PCE in Soil Gas
Samples of soil gas collected at multiple depths at several locations across the plume showed concentrations of PCE as
high as 170,000 micrograms per cubic meter (µg/m3) on mall property and as much as 46,000 µg/m3 in shallow soil gas
within the residential neighborhood. The NDEP performed vapor-transport monitoring using the data from soil-gas
samples. The results from NDEP’s modeling, along with toxicity information from the USEPA, prompted the NDEP to
offer indoor air sampling to residents whose homes were potentially affected by PCE vapors emanating from
groundwater.
PCE in Indoor Air
Based on data collected in more than 97 homes, elevated concentrations of PCE vapors in indoor air appear restricted to
homes overlying or adjacent to the 100 µg/L boundary for PCE in groundwater. Annual indoor air sampling is being
offered to owners of these homes. If PCE concentrations measured in any home exceed the NDEP’s interim-action level
of 32 µg/m3, a mitigation system is offered at no charge to the home owner.
What are the Uses and Effects of PCE?
The contaminant of concern is perchloroethylene, also known as tetracholoroethylene, tetrachloroethene, “perc”, or PCE. It is a
colorless, nonflammable liquid that does not occur naturally. PCE is a solvent/degreaser used by dry cleaners to clean fabrics, and is
also found in some common household products, such a glues, spot cleaners, brake parts cleaners, and some spray polishes.
In December, 2012, the US EPA revised its hazard summary for PCE. See: http://www.epa.gov/ttn/atw/hlthef/tet-ethy.html
Proposed Plan for the Maryland Square PCE Site
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II.
HISTORY OF SITE INVESTIGATIONS
The following text provides a brief chronology of the investigations conducted for the Maryland Square PCE Site. The
complete administrative record is available for review by the public at the Carson City offices of the NDEP and on-line at
http://ndep.nv.gov/pce/maryland_square.htm .
November 29, 2000
The PCE found at the site of the former dry cleaner was first reported to NDEP’s spill reporting hotline on November 29,
2000. The historical release was discovered during a routine environmental site assessment performed as part of a
property transaction. Results from the investigation were submitted to the NDEP on July 21, 2001. After reviewing the
report, NDEP determined that more investigation was required to evaluate whether the PCE had migrated offsite.
2001 to 2004
In 2001, the property owner began investigation of soil and groundwater at the site of the former dry cleaner. A 2002
report provided data showing PCE-contaminated soils below the concrete slab of the former dry cleaning shop.
Additional monitoring wells provided data for groundwater directly downgradient (east) of the dry cleaners.
A report released in May, documented the highest concentration of PCE in a new well (MW-13) downgradient from the
dry cleaners and east of S. Maryland Pkwy. This 2003 report concluded that “Based on the information provided in this
report and previous reports, it appears that the source of the PCE contamination originates at the Al Phillips The
Cleaners, Inc.’s dry cleaning facility.” Wells installed in 2003 and 2004, failed to find the eastern boundary of the plume.
2005 to 2008
In March, 2005, five new monitoring wells were installed in the Paradise Palms neighborhood, and results were provided
in a July 2005 report. This 2005 report presented the first data showing that the PCE plume had migrated more than
2,000 feet east of the source area and extended beneath the residential neighborhood east of Boulevard Mall. The NDEP
then required the responsible party to submit a Corrective Action Plan for the cleanup of soil and groundwater. In April
2006, more wells were installed farther to the east indicated that the Maryland Square PCE plume was atypically long
compared with other PCE sites in Las Vegas and extended at least several thousand feet from the source area.
In early 2007, a detailed investigation of source area soils was completed, along with an initial assessment of PCE vapors
in soil gas overlying the PCE plume in groundwater. Based on data for groundwater and soil gas and the results from the
NDEP’s modeling of the PCE concentrations in soil gas samples, the NDEP determined that action was needed to further
evaluate the potential for intrusion of PCE vapors into the homes overlying the PCE-contaminated groundwater.
The NDEP moved forward with a plan to perform indoor air sampling of homes in the Paradise Palms neighborhood. In
August 2007, the NDEP mailed notification letters and information packets to approximately 150 residents and property
owners, and a press release was issued. Staff from the NDEP met with residents in their homes for personal meetings to
answer questions, provide information, and obtain permission to sample the indoor air at the residence.
With permission of the residents, contractors working for the NDEP collected samples of indoor air from homes,
following general USEPA guidelines for sampling indoor air at vapor intrusion sites. The NDEP sent sample results to
each resident whose home was sampled. Representatives from the NDEP met with all interested homeowners to
discuss their sample results and answer their questions. Ultimately, indoor air was tested in 97 homes and two schools.
Home mitigation systems were installed in 14 homes in 2008, at no cost to the home owners.
2009 to 2012
On May 4, 2009, the NDEP filed a complaint in U.S. District Court against the former owners and operators of the facility.
On December 27, 2010, U.S. District Court issued a Permanent Injunction against the former owners and operators of
the facility. The injunction established the schedule for remediation of PCE-contaminated soil and groundwater at the
site. It also decreed that groundwater monitoring should continue based on the schedule previously defined by the
NDEP, and that testing of indoor air should be offered annually to potentially affected homeowners.
Proposed Plan for the Maryland Square PCE Site
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In the fall of 2011, source-area soil contaminated with PCE was excavated and properly disposed of in offsite facilities.
The floor of the excavation, which extended down to the water table at about 18 feet deep, was treated with the
chemical oxidant, potassium permanganate (KMnO4) to promote chemical destruction of residual PCE, prior to
backfilling. The excavation was backfilled with clean soil and re-grading of the site was completed in late October, 2011.
2013 and 2014
The vertical extent of the PCE-contaminated groundwater was established by drilling deeper borings as deep as 120 feet
on the Boulevard Mall property, directly downgradient from the former dry cleaners. Groundwater data collected from
deep borings and wells indicated that concentrations of PCE taper off below about 70 feet, reaching largely
nondetectable levels by about 80 feet. Data from samples collected at different depths indicate that the PCE plume is
largely constrained to the upper 60 feet of groundwater. This shallow groundwater is not used for drinking water.
Pilot testing of several cleanup technologies was performed in the eastern parking lot of the Boulevard Mall, just
upgradient of the residential neighborhood. The testing focused on injection of two types of oxidants: potassium
permanganate and peroxide-activated ozone, for “in situ chemical oxidation” (ISCO) to clean up groundwater. Although
results were initially promising, data collected from 3 to 12 months after the injections appeared to show that PCEcontaminated groundwater had been displaced into previously clean areas. These results suggested that any cleanup
technology involving injection of treatment chemicals must be paired with groundwater withdrawal to minimize the
displacement of contaminated groundwater.
By 2014, new wells delineated the eastern end of the plume, approximately 6,000 feet downgradient from the source at
the former dry cleaners. The cigar-shaped plume of PCE-contaminated groundwater is from 400 to about 1,000 feet
wide. The shape of the plume is consistent with a single source at the site of the former dry cleaners in the former
Maryland Square Shopping Center. The plume terminates at the 5 µg/L boundary about 1,000 feet east of Eastern Ave.
Determining the shape and size of a contaminant plume in groundwater is a methodical step-by-step process that requires installing
a series of borings and monitoring wells. Samples of groundwater collected from the wells are analyzed to determine if the
contaminant is present at that well location. This process is followed by the installation of additional wells in the direction of
groundwater flow, until the extent of the plume is defined. The history of well installations is shown at:
http://ndep.nv.gov/pce/doc/maryland_square_well_monitoring_history3.jpg.
III.
SCOPE AND ROLE OF RESPONSE ACTION
The remediation of groundwater follows the initial interim actions performed by the NDEP; these actions included
testing of indoor air in residences overlying the contaminated groundwater and the installation of home mitigation
systems in those homes found to be adversely affected by intrusion of PCE vapors. The proposed remediation of
groundwater also follows cleanup of the source-area soils at the site of the former dry cleaners.
Cleanup of groundwater is needed to decrease concentrations of PCE in groundwater to a level that is protective of
indoor air, at which point the home mitigation systems will no longer be needed to protect human health from
contaminant vapors. Cleanup actions are also intended to prevent further degradation of groundwater quality.
IV.
SUMMARY OF SITE RISKS
Exposure to contaminants at the Maryland Square PCE Site occurs through inhalation of contaminant vapors that have
accumulated in homes via the vapor intrusion pathway. The contaminant vapors emanate from the contaminated
groundwater. PCE is the main chemical of concern at the site; however, degradation products and impurities in the
original dry cleaning solvent may include TCE, DCE, and vinyl chloride.
The contaminant plume is contained in the shallow groundwater system, which is underlain by hundreds of feet of
layered sediments, including a thick sequence of low-permeability clays. These layers provide a barrier to vertical
migration of contaminated groundwater, which protects the drinking water aquifer. City-supplied drinking water is not
affected by this contamination.
Proposed Plan for the Maryland Square PCE Site
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A screening-level human health risk assessment was performed for the Maryland Square PCE Site. The work was
consistent with the Risk Assessment Guidance for Superfund (U.S. Environmental Protection Agency, 1989), and
included four basic steps: (1) data evaluation and identification of contaminants of potential concern, (2) exposure
assessment, (3) toxicity assessment, and (4) risk and hazard characterization.
The risk estimate used data from indoor air samples collected at houses in the residential neighborhood. The chemicals
evaluated in the screening-level human health risk assessment included PCE, TCE, and vinyl chloride. Each house was
evaluated as an individual “exposure unit,” meaning that exposures were considered separately for each home, rather
than averaging the risk.
In late 2012, the USEPA released the new toxicity assessment for PCE. The USEPA’s new toxicity factors found that PCE is
slightly less toxic from a carcinogenic perspective, but more toxic than previously believed for non-carcinogenic effects,
which are mainly neurological effects. The greatest carcinogenic risk at the Maryland Square PCE Site was estimated to
be 3 per 100,000 excess cancers due to long-term exposure to PCE by inhalation of contaminated indoor air. The
greatest noncarcinogenic hazard index was estimated to be 2.6 times greater than acceptable levels.
Some private wells screened in the shallow groundwater system were indicated in some areas east of Eastern Avenue,
according to online records in the Nevada Division of Water Resources database. For this reason, it was necessary to
delineate the eastern end of the plume to the 5 µg/L drinking water standard for PCE. According to records at the
Nevada Division of Water Resources, there are no private wells within the 5 µg/L boundary of the plume.
V.
REMEDIAL ACTION OBJECTIVES
The overall objective of the groundwater cleanup is to protect human health and the environment by reducing
concentrations of PCE in groundwater and minimizing exposure of receptors to affected media. This objective requires
the development and implementation of suitable and effective cleanup technologies. Until the cleanup of groundwater
is achieved, interim actions (i.e., home mitigation systems) will continue. To accomplish the overall objective, the
following goals (Figure 3) have been established:
1. Protect human health by reducing inhalation exposure to PCE and daughter products emanating from groundwater
and ensuring that concentrations of PCE in indoor air are less than the long-term goals of 9.4 µg/m3 for PCE and 6.0
µg/m3 for TCE.
2. Remediate shallow groundwater where PCE concentrations exceed the remediation standard for groundwater
protective of indoor air (100 µg/L).
3. Execute appropriate action to ensure PCE does not exceed water quality standard of 5 µg/L as defined in NAC
445A.22735 in domestic water supply wells, and to protect water quality from further degradation.
VI.
SUMMARY OF REMEDIAL ALTERNATIVES
Remedies were developed to address shallow groundwater contaminated with the dry cleaning chemical, PCE. The
NDEP evaluated five remedial alternatives.
Alternative 1 – No Further Action Alternative
Alternative 2 – Enhanced Bioremediation for In Situ Treatment of Target Areas
Alternative 3 – Permeable Reactive Barrier (PRB) using Zero-Valent Iron (ZVI)
Alternative 4 – In Situ Chemical Oxidation (ISCO) of Entire Plume
Alternative 5 (Preferred Alternative) – Groundwater Extraction and Treatment (East Parking Lot), with Air Sparging and
Vapor Extraction (AS/VE) or in situ chemical oxidation (ISCO) with Re-circulation of Groundwater (West Parking Lot)
Proposed Plan for the Maryland Square PCE Site
Page 7 of 20
Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 8 of 20
Figure 3. General areas of the Maryland Square PCE plume, as related to remedial action objectives
Common Elements
All of the alternatives require maintaining the protective elements already in place at the Site until groundwater cleanup
levels are achieved. These common elements include long-term monitoring of groundwater and indoor air to monitor
contaminant concentrations across the site. Another common element is the use of institutional controls (ICs) to prevent
installation of drinking water or irrigation wells within the footprint of the PCE plume. Additionally, all alternatives
require maintenance of home mitigation systems (such as system adjustment and fan replacement), along with annual
testing of indoor air for homes located on or within the estimated 100 µg/L boundary of the plume
All of the remedial alternatives would require a five-year review. The five-year reviews of the remedy would be
conducted until the performance standards for groundwater and indoor air are achieved. If the indoor air goal is
achieved but the remediation goal is not, the 100 µg/L goal for the concentration PCE in groundwater may be revised
upward as long as protection of indoor air is well demonstrated and well documented.
VII. EVALUATION OF REMEDIAL ALTERNATIVES
The evaluation of each alternative is used as a method to compare and contrast the remedial alternatives and assess the
advantages and disadvantages of each by looking at a number of important factors. The expectations for remedy
selection are listed in the Code of Federal Regulations at 40 CFR § 300.430 (a)(1)(iii).
Threshold criteria are requirements that each alternative must meet in order to be eligible for further evaluation and
selection. Primary balancing criteria are used to weigh major trade-offs among alternatives. In the final balancing of
trade-offs between alternatives, the modifying criterion (community acceptance) is of equal importance to the primary
balancing criteria. In this Proposed Plan, each remedial alternative was evaluated according to the threshold and
primary balancing criteria. Community acceptance will be evaluated after public comments are received on this
Proposed Plan.
Threshold Criteria
(1) Overall Protection of Human Health and the Environment – this criterion addresses how the alternative achieves
and maintains protection of human health and the environment
(2) Compliance with Cleanup Standards – this criterion addresses how the alternative performs relative to water
management objectives, requirements and water quality laws
Proposed Plan for the Maryland Square PCE Site
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Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 9 of 20
Primary Balancing Criteria
(3) Long-term Effectiveness and Permanence – this criterion addresses the long-term effectiveness of alternatives in
maintaining protection of human health and the environment and their relative permanence. It is an assessment of
how the system will perform years into the future.
(4) Reduction in Toxicity, Mobility, and Volume through Treatment – this criterion addresses the ability of the
alternative to permanently or significantly reduce toxicity, mobility or volume of contaminants. It addresses the type
and quantity of treatment residuals remaining at the site, and the degree to which treatment reduces the inherent
hazards posed by principal threats at the site
(5) Short-term Effectiveness –this criterion addresses the impacts of the alternative during construction and
implementation, until the project’s initial objectives and goals are met. The criterion is also used as a measure of
how quickly an alternative can meet remedial action objectives.
(6) Implementability – this criterion addresses the technical and administrative feasibility of implementing an
alternative and the availability of services and materials, including technical difficulties and unknowns associated
with the construction and operation of a technology and the ability to monitor the effectiveness of the remedy
(7) Cost – this criterion addresses the capital and operations and maintenance costs of each alternative
Modifying Criterion (evaluated after public comments are received)
(8) Community Acceptance – this criterion is evaluated after public comments are received. All comments received
during the 60-day review period and at the public meeting (to be held during the review period), will be addressed
and included in the “Responsiveness Summary” in the Record of Decision (ROD), which will document the selected
remedy.
Alternative 1: No Further Action
Estimated Cost: $0
Estimated Annual Cost: $0
Estimated Present Worth Cost: $0
Estimated Time to Completion: hundreds of years
Description of Alternative 1. Under this alternative, no further actions would be taken to prevent exposure to the
contaminated air and groundwater at the Site. Additionally, no action would be taken to clean up the groundwater.
Threshold Criteria. The no further action alternative fails to meet the threshold criteria of protecting human health and
achieving action levels for PCE in groundwater. This alternative was developed and retained as a baseline scenario to
which the other alternatives may be compared. If concentrations of PCE in groundwater are not reduced and if
migration of contaminated groundwater is not limited, then operation of home-mitigation systems must continue for
the life of the plume, or residents will continue to be exposed via vapor intrusion. Untreated, the PCE plume at this site
could persist for centuries.
The contaminated groundwater is currently posing a potential health risk to residents in the neighborhood, and the
greatest mass of PCE still remains in groundwater upgradient of the neighborhood. A stable or expanding plume, along
with the continued migration of PCE-contaminated groundwater into the neighborhood, has the potential to continue or
extend vapor exposure risk to residential receptors. For these reasons, the no further action alternative is not
acceptable at this site. The remaining four alternatives were evaluated against threshold and primary balancing criteria.
Proposed Plan for the Maryland Square PCE Site
Page 9 of 20
Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 10 of 20
Threshold Criteria
Overall Protection of
Human Health and the
Environment
•
Achievement of
Action Levels
•
Likelihood that the Alternative will Adequately
Protect Human Health and the Environment
Likelihood that the Alternative will
Achieve Cleanup Goals for all Media
Primary Balancing Criteria
Long-Term
Effectiveness and
Permanence
•
•
Expected Magnitude
of Residual Risk
Adequacy and
Reliability of Controls
Reduction of Toxicity,
Mobility or Volume
through Treatment
•
•
•
•
•
Short-Term
Effectiveness
Treatment Process Used
and Materials Treated
Estimated Amount of
Hazardous Materials
Treated or Destroyed
Expected Reduction in
Toxicity, Mobility or
Volume
Degree to which
Treatment is
Irreversible
Type and Quantity of
Residual Contaminants
Remaining after
Treatment
•
•
•
•
Protection of
Community during
Remedial Actions
Protection of
Workers during
Remedial Actions
Effects to the
Environment
Estimated Time
until Remedial
Action Objectives
are Achieved
Implementability
•
•
•
•
•
•
Ability to Construct
and Operate the
Technology
Reliability of the
Technology
Ease of Undertaking
other Technologies
Ability to Monitor
Effectiveness of
Remedy
Availability of Offsite
Treatment & Disposal
Availability of
Equipment &
Operators
Cost
•
•
•
Estimated Capital
Costs
Estimated Annual
O&M Costs
Estimated PresentWorth Costs
Modifying Criterion
Community
Acceptance
•
•
•
Features of the Remedial Alternative that the Community Supports
Features of the Remedial Alternative about which the Community has Reservations
Elements of the Remedial Alternative the Community Strongly Opposes
Alternative 2: Enhanced Bioremediation for In Situ Treatment of Target Areas
Estimated First-Year Cost: $600,000
Estimated Annual Cost: $450,000
Estimated Present Worth: $3,100,000to $5,300,000
Estimated Time to Completion: 10+ years
Description of Alternative 2
Enhanced Bioremediation involves the establishment (and maintenance) of suitable geochemical conditions in
groundwater necessary to sustain populations of microbes that perform dechlorination of PCE under anaerobic
conditions. Such conditions may also establish abiotic dechlorination on mineral surfaces. Anaerobic dechlorination is a
step-wise process that progressively strips chlorine atoms from the carbon framework of PCE (C2Cl4) to form TCE
(C2Cl3H), then DCE (C2Cl2H2), then vinyl chloride (C2Cl1H3), then ethene (C2CH4), and ultimately, carbon dioxide (CO2).
Figure 4 shows the treatment area for the in situ treatment using enhanced bioremediation.
Proposed Plan for the Maryland Square PCE Site
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Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 11 of 20
Figure 4. Map showing treatment area for Alternative 2, Enhanced Bioremediation
To stimulate and enhance microbial activity, microorganisms or amendments are injected into groundwater.
Amendments can be injected where the bacteria necessary to degrade the contaminants are present but conditions do
not favor their growth. Microorganisms can be injected when the bacteria necessary to degrade the contaminants do
not occur naturally at a site or occur at too low of a population to be effective. This remedy would consist of drilling
injection wells in selected treatment areas and injecting amendments and anaerobic bacteria to actively dechlorinate
and degrade the PCE “in situ” in the groundwater.
Threshold Criteria. At sites where geochemical and lithologic characteristics are suitable, enhanced bioremediation has
successfully remediated PCE to achieve action levels and protect human health.
Long-term Effectiveness and Permanence. The long-term effectiveness of this family of technologies is suspect because
anaerobic conditions are not naturally present at the site, and such conditions would be difficult to induce and sustain.
Implementation of this alternative would require creating and maintaining strongly reducing conditions in the
groundwater so that dechlorinating microorganisms could thrive. Addition of a bacterial culture would likely be required
to avoid long lag periods before such microbial populations could develop sufficiently. Bioreactors would have to deal
with sulfide toxicity, whereby the waste products of the microorganisms eventually become toxic to the microbes
themselves. This can eliminate or reduce all microbial activity or cause these microbes to be replaced by other bacteria
that will not dechlorinate PCE.
Reduction of Toxicity, Mobility or Volume. A potential problem with any reductive technology is that the daughter
products of PCE degradation (TCE, DCE, and vinyl chloride), are more toxic than PCE; therefore, this technology has the
potential to increase toxicity due to incomplete degradation, even if the mass of PCE decreases. Additionally, sulfate
reduction produces sulfide, which is toxic to the dechlorinating bacteria. The high concentrations of naturally occurring
sulfate (as much as 3,700 mg/L) could therefore result in partial dechlorination of PCE, resulting in increased
concentrations of TCE, DCE or vinyl chloride in the groundwater.
Proposed Plan for the Maryland Square PCE Site
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Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 12 of 20
Short-term Effectiveness. It is unknown if treatment could even temporarily create conditions that are sufficiently
reducing to fully dechlorinate the PCE. As noted above, partial dechlorination of PCE produces more toxic compounds,
such as TCE. Even if it were possible to overcome naturally occurring electron acceptors (including dissolved oxygen,
nitrate, sulfate, and ferric iron) and create reducing conditions in groundwater, such reducing conditions would be
difficult to maintain. As upgradient groundwater flowed into the treatment zone, the geochemistry in the treatment
area would revert back to conditions that are not favorable for anaerobic dechlorination.
Implementation. Enhanced bioremediation in targeted areas upgradient of the residential neighborhood would
theoretically achieve threshold criteria; however, the geochemistry of shallow groundwater at the Maryland Square PCE
Site is not conducive to these types of “reductive technologies.” It is unknown if treatment could even temporarily
create sufficiently reducing conditions to fully dechlorinate the PCE. Therefore, it is questionable that enhanced
bioremediation could adequately protect human health or achieve cleanup levels for PCE in groundwater.
Cost. Cost for this type of technology is based on size and mass of the PCE plume; however, implementation may be
logistically infeasible and costs may be more than $5,000,000.
Alternative 3: Permeable Reactive Barrier (PRB) using Zero-Valent Iron (ZVI)
Estimated First-Year Cost: $1,500,000
Estimated Annual Cost: $600,000
Estimated Present Worth: $4,600,000 to $7,600,000
Estimated Time to Completion: 10+ years
Description of Alternative 3
A permeable reactive barrier (PRB) is a constructed zone of reactive material that extends below the water table to
passively intercept and treat contaminated groundwater. PRBs can be installed as permanent or semi-permanent units.
The most commonly used PRB configuration is that of a continuous trench in which the treatment material is backfilled.
The trench is perpendicular to and intersects the groundwater plume (Figure 5).
Figure 5. Map showing treatment area for Alternative 3, Permeable Reactive Barrier
Proposed Plan for the Maryland Square PCE Site
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Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 13 of 20
Installation of PRBs at depths greater than 70 feet can be challenging. At the Maryland Square PCE Site, a north-south
trench in the east parking lot of the Mall would need to extend to a depth of approximately 80 feet. The primary
determinant of degradation rate is the specific surface area of the PRB, or the surface area of iron per unit volume of
pore water. The use of a passive PRB requires comprehensive hydrologic characterization, so that the design can be
based on a thorough understanding of the heterogeneity of subsurface soils.
Threshold Criteria. PRBs using zero-valent iron (ZVI) have been shown to be effective in intercepting and treating
chlorinated VOC plumes at some sites, achieving action levels and protecting human health. Properly designed PRBs are
permeable barriers that should have little effect on groundwater flow patterns. A PRB employing ZVI installed
upgradient of the residential neighborhood would allow groundwater to flow into the neighborhood, but without
dissolved-phase PCE. In the presence of ZVI (granular iron or iron filings) chlorinated solvents like PCE degrade to
nontoxic end products. This abiotic process involves corrosion (oxidation) of ZVI and reduction of dissolved chlorinated
VOCs. The process induces highly reducing conditions that cause substitution of chlorine atoms by hydrogen in the
structure of chlorinated solvent. Under ideal geochemical conditions, once installed, such systems should require little
maintenance.
Long-term Effectiveness and Permanence. Use of PRBs with ZVI has been shown to be effective in intercepting and
treating chlorinated VOC plumes at some sites. A PRB employing ZVI installed upgradient of the residential
neighborhood would theoretically achieve threshold criteria; however, the site conditions are likely to preclude effective
long-term functioning of this technology. Under the geochemical conditions at the Maryland Square PCE Site the ZVI
would be subject to premature passivation (i.e., loss of its catalytic properties) due to the naturally high concentrations
of total dissolved solids and sulfate in site groundwater. The concentrations of naturally occurring constituents are in
ranges known to diminish the longevity of ZVI-based PRBs, due to mineral precipitation and other surface-coating
reactions . It is not known how quickly the ZVI in the PRB would suffer passivation and breakthrough. Before passivation
occurred, PCE could be at least partially dechlorinated by ZVI-mediated reactions.
The high concentrations of naturally occurring sulfate also have the potential to enhance the growth of sulfate-reducing
bacteria that feed off of the hydrogen released during iron corrosion. Excessive growth of sulfate reducers can cause
biofouling, which in turn can cause preferential flow through the barrier and reduce the hydraulic residence time.
Certain sulfate-reducing bacteria can partially dechlorinate PCE to cis-1,2 DCE at the leading edge of the barrier.
Increasing the concentration of cis-1,2 DCE (which is degraded more slowly than PCE), coupled with the decreased
residence times, can result in breakthrough of PCE and its daughter products. Depending on the severity of the
biofouling, groundwater flow may eventually bypass the PRB.
Long-term effectiveness and permanence are questionable for the reasons provided above. This technology is not
considered to provide long-term effectiveness due to site geochemistry, which would likely lead to failure of the remedy
in the longer term, even if initial results showed decreased concentrations of PCE downgradient of the PRB.
Reduction of Toxicity, Mobility or Volume. Dechlorination would reduce the mass of PCE, but if the PCE is only partially
dechlorinated, the daughter products TCE and vinyl chloride could accumulate. These two degradation products are
more toxic than PCE, so partial dechlorination upgradient of the neighborhood could actually make exposure problems
worse. So this technology may not result in the reduction of toxicity through treatment. The ZVI could be initially
successful in achieving full dechlorination of the PCE; however, partial dechlorination may occur after passivation of
reactive surfaces increases over time.
Short-term Effectiveness. Short-term effects include the disruption of the eastern parking lot at the Mall and noise and
dust related to excavation and placement of the PRB. The location of the PRB would be next to the residential
neighborhood, so the noise and dust during construction could be disruptive.
Implementation. It may be logistically difficult to implement this remedy. Although it may be possible to install a PRB to
the base of the plume (approximately 80 feet deep on the east side of the Mall), specialized excavation equipment
would likely be required. Implementation of this remedy, if possible, would be difficult.
Cost. This alternative has a high initial cost, but typically has lower operational and maintenance costs than more active,
mechanical alternatives, such as air sparging and vapor extraction.
Proposed Plan for the Maryland Square PCE Site
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Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 14 of 20
Alternative 4: In Situ Chemical Oxidation (ISCO) of Entire Plume
Estimated First-Year Cost: $1,100,000
Estimated Annual Cost: $700,000
Estimated Present Worth: $5,800,000 to $8,700,000
Estimated Time to Completion: 10+ years
Description of Alternative 4
A chemical oxidation reaction involves the breaking of chemical bonds and the removal of electrons. In situ chemical
oxidation is a class of remediation technologies in which PCE and other contaminants are degraded in place by oxidants
delivered to the subsurface. Successful implementation of this technology requires an effective means for dispersing the
oxidizing chemicals throughout the contaminated groundwater. Complete and rapid treatment may be inhibited by a
lack of direct contact of oxidant and contaminant. This is especially true for highly heterogeneous soils with lowpermeability lenses and layers. To employ ISCO across the entire plume would involve drilling numerous injection wells
and thorough characterization of every treatment area. Oxidants could be mixed on site, but safety and access issues
may affect the ability to conduct ISCO everywhere across the plume (Figure 6).
Figure 6. Map showing Treatment Area for Alternative 4, In Situ Chemical Oxidation of Entire Plume
Threshold Criteria. In-situ chemical oxidation (ISCO) involves the injection of oxidant solutions into the subsurface, and
ISCO has been successfully used for treating PCE in soils and groundwater at some sites. Under ideal conditions, ISCO
technology has the potential to attain the threshold criteria of protecting human health and achieving action levels.
Long-term Effectiveness and Permanence. Initial results from ISCO pilot tests performed at the Maryland Square PCE
Site showed large decreases (order of magnitude) in the concentration of PCE; however, data collected six and nine
months after the pilot-test injection of 20,000 gallons of permanganate solution showed that concentrations of PCE in
deep-screened wells increased from near nondetect (0.50 and 0.68 µg/L) to 710 to 160 µg/L PCE in one well, and near
nondetect (0.66, 0.50 µg/L) to 25 to 62 µg/L in another well. Long-term effectiveness is difficult to assess because it is
difficult to distinguish between destruction of PCE in groundwater and displacement of PCE-contaminated groundwater.
Proposed Plan for the Maryland Square PCE Site
Page 14 of 20
Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 15 of 20
Reduction of Toxicity, Mobility or Volume. Laboratory tests have demonstrated that chemical oxidants destroy PCE.
However, in the field, it is more difficult to predict and direct the migration of oxidants and contaminants. The presence
of heterogeneous soils and clay layers exacerbate the difficulty in controlling and predicting migration of contaminants
and oxidants. Unless injection of oxidant solutions into groundwater is paired with extraction of groundwater, the
potential for uncontrolled migration is too high to recommend use near a residential area. The issue of displacement
also can make it difficult to accurately gauge the effectiveness of the ISCO treatment in reducing the toxicity, mobility or
volume of the PCE. That is, it is difficult to determine if decreasing concentrations measured in some observation wells
are the result of chemical destruction of the PCE or simply displacement of PCE-contaminated groundwater.
The injection of large amounts of water into a contaminated area will dilute the amount of contamination present. An
issue that must be resolved when assessing treatment effectiveness is the role of displacement of contaminated water
away from the injection points. Depending on sampling locations observed, post-injection declines might reflect the
displacement of contaminated water rather than actual contaminant mass destruction. Any area where oxidants are
injected needs to have a comprehensive monitoring well system in place. Monitoring should start before oxidant
injection and continue at least a year after.
Short-term Effectiveness. Conducting ISCO within the residential area would likely encounter numerous problems
related to infrastructure and access, as well as the noise and disruption of traffic flow throughout the neighborhood.
There are also safety issues related to the chemical oxidant itself and the migration of the oxidizing solution into
unintended areas. Although the data from the pilot test indicated that concentrations of PCE and its daughter products
were almost completely destroyed by the oxidant, the effects of dilution and displacement after injecting the chemical
oxidant were not calculated.
Implementability. Each chemical oxidant type has specific drawbacks to implementation such as potential permeability
issues associated with manganese precipitation with permanganate, or potential volatilization from the exothermic
reactions associated with either persulfate or Fenton’s reagent, any of which can cause issues for the residents.
Additional concerns include the hazardous nature of the oxidants themselves, which could pose safety concerns for
anyone who unknowingly comes into contact with them. Use of ISCO injections in the residential area is problematic
due to widespread infrastructure. Access may also be an issue.
Cost could be relatively high. The Correction Action Report estimated that treatment of the portion of the plume
upgradient of the neighborhood would be $3,000,000 to $5,000,000.
Alternative 5 (Preferred Alternative): Groundwater Extraction and Treatment (East Parking Lot), with Air
Sparging and Vapor Extraction or ISCO with Recirculation of Groundwater (West Parking Lot)
Estimated First-Year Cost: $1,700,000
Estimated Annual Cost: $650,000
Estimated Present Worth: $5,700,000 to $7,900,000
Estimated Time to Completion: 10+ years
Description of Alternative 5
This alternative consists of two treatment areas: in the eastern part of the mall property, pumping wells will provide
hydraulic containment that will greatly reduce the flow of PCE-contaminated groundwater into the residential
neighborhood; in the western part of the mall property, one or more technologies will be used to destroy or remove
contaminants in the main mass of the plume (Figure 7).
Threshold Criteria. A well-designed groundwater extraction and above-ground treatment is a proven technology that
will also prevent continued migration of PCE-contaminated groundwater into the neighborhood. Treatment
technologies being considered to address the high mass remaining near the source, such as AS/VE systems, have proven
effective in removing contaminants at other sites in the Las Vegas Valley. Chemical oxidation, another treatment
technology being considered, has been shown in laboratory tests to effectively destroy PCE and its degradation
products. The combination of containment and treatment are expected to achieve action levels, thereby protecting
human health and the environment.
Proposed Plan for the Maryland Square PCE Site
Page 15 of 20
Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 16 of 20
Long-term Effectiveness and Permanence. This remedy combines three technologies to maximize effectiveness and
permanence of the cleanup. Destruction of the mass of PCE just east of the former dry cleaners, combined with
containment and aboveground treatment of extracted PCE-contaminated groundwater will permanently reduce the
mass of PCE in the plume.
Reduction of Toxicity, Mobility or Volume. The pump and treat portion of the remedy will provide hydraulic
containment of PCE-laden waters and reduce the mass of PCE flowing into the residential neighborhood. Aboveground
treatment, AS/VE and ISCO will reduce the volume (mass) of PCE in groundwater.
Short-term Effectiveness. The extraction wells will hydraulically contain the flow of PCE-contaminated groundwater.
Implementability. Design and installation of remedy components are easy to implement using widely available drilling
technology. Detailed characterization of treatment areas would be required for any of the remedies; better
characterization leads to better design and better effectiveness of the remedy.
Cost: Cost estimated for this alternative includes annual operating and maintenance expenses.
Figure 7. Map showing treatment area for Alternative 5, the Preferred Alternative
VIII. PREFERRED ALTERNATIVE
Alternative 5, Groundwater Extraction and Treatment (East Parking Lot), with Air Sparging and Vapor Extraction or ISCO
with Recirculation of Groundwater (West Parking Lot), is the Preferred Alternative. This alternative is recommended
because it will achieve substantial risk reduction by reducing the mass of PCE near S. Maryland Parkway and preventing
the continued flow of contaminated groundwater into the residential neighborhood (Figure 7).
The major elements of the Preferred Alternative include the following:
•
Construction of a groundwater extraction and treatment (also known as “pump and treat”) system for hydraulic
containment of the PCE plume upgradient of the residential neighborhood.
Proposed Plan for the Maryland Square PCE Site
Page 16 of 20
Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 17 of 20
•
AS/VE or ISCO with directed recirculation of groundwater (that is, paired injection and extraction wells) in the area
of highest concentrations on the west side of the Boulevard Mall
•
Continued monitoring of groundwater across the site
•
Indoor air monitoring of qualifying homes in the residential neighborhood between the Boulevard Mall on the west
and the Las Vegas National Golf Course on the east
Maintenance of home mitigation systems (SSD systems) and installation of new mitigation systems in homes as needed,
until such time that concentrations of PCE in the groundwater have declined to be sufficiently protective of residential
indoor air via the vapor intrusion pathway
Remediation of groundwater using extraction and aboveground treatment (“pump and treat”) remains a dependable
technology for cleanup of deep (> 50 feet below ground surface) groundwater. Successful and cost-effective use of this
technology requires (1) detailed characterization of the geology, hydrology, and chemistry; (2) removal of source terms,
if possible; (3) initial design for plume containment and source remediation; (4) detailed monitoring of the remediation;
(5) active ongoing reevaluation of the operating well field, including redesign as appropriate (dynamic management); (6)
reinjection of treated groundwater to speed the flushing of contaminants. Techniques can dramatically reduce the time
required to achieve cleanup goals and thus the cost of groundwater remediation.
This remedy combines at least two remedial technologies to achieve containment of the PCE-contaminated
groundwater and to reduce the mass of contaminants through treatment. Hydraulic containment of the PCE plume
upgradient of the residential neighborhood would be achieved by installing a line of pumping wells to prevent
contaminated groundwater from continuing to flow into the neighborhood. A series of extraction wells would be
designed to intercept the PCE-contaminated groundwater upgradient of the neighborhood. Groundwater would be
extracted, treated aboveground to remove the contaminants, then re-injected as clean water to help reduce
concentrations of PCE in the plume underlying the neighborhood. The reinjection should accelerate the time required to
reduce concentrations of PCE to the point where home mitigation systems are no longer needed.
Another component of the remedy will be treatment of the main mass of contaminated groundwater which currently
resides in an area just to the east of the former dry cleaner, in the western parking lot at the Boulevard Mall. This
component may actually involve several different treatment technologies, such as air sparging and vapor extraction
(AS/VE) or in situ chemical oxidation (ISCO) with directed recirculation that is designed to prevent pushing the
contaminated groundwater into areas that are currently not contaminated. This component of the groundwater remedy
may include any or all of the following:
•
AS/VE, where vapor extraction is used to capture fugitive vapors released from the groundwater by the sparging
of air into the groundwater
•
In situ oxidation (ISCO), with concurrent groundwater extraction (i.e., directed recirculation) to minimize
displacement of contaminated groundwater into areas or zones that are currently unaffected by the PCE plume.
Pump and Treat (Groundwater Extraction and Aboveground Treatment)
“Pump and treat” involves groundwater extraction and aboveground treatment of the extracted groundwater. This
technology will require a more detailed assessment of the aquifer properties and the contaminant profile in the vicinity
targeted for well placement. The aquifer tests performed on the Mall portion of the site suggested that the site is a
candidate for this remediation technology. Assuming that the hydraulic properties are similar across the length and
breadth of the plume, this site would be amenable to pump and treat. The design of an effective extraction system will
require additional aquifer testing. Dewatering wells are common throughout the Las Vegas Valley, mainly for
underground parking areas at some of the large hotels, so it should be possible to achieve drawdown and reasonable
rates of extraction. Injection of cleaned groundwater into the “stagnant zone” downgradient of the pumping wells can
be used to help dilute and flush out the PCE-contaminated groundwater under the residential neighborhood.
Proposed Plan for the Maryland Square PCE Site
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Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 18 of 20
Aboveground treatment can include air stripping, activated carbon adsorption, or other methods. The selection of pump
and treat and the specific aboveground treatment needs to consider the concentration of contaminant in the extracted
water, the pumping rate/volume of extracted water, permitting requirements, exhaust treatment requirements, and
public acceptance including noise control concerns, site logistics, and cost. Those factors would be addressed during the
preliminary design phase. Depending on the quality of the treated water, and any regulatory constraints, the treated
water might be suitable for supplementing the irrigation demand at the Mall or golf course.
Air Sparging and Vapor Extraction
Air sparging is performed “in situ” and therefore offers the benefit of not bringing contaminated groundwater to the
surface; however, this technology offers less direct plume control than the pump and treat alternative. For this reason,
AS/VE is only being proposed for the western parking lot of the Mall, because this area is not adjacent to any residences.
Sparging systems are simple in design, require little operation and maintenance (O&M), require a small footprint, and
are relatively inexpensive. Vapor extraction is needed to capture the PCE vapors to prevent potential vapor intrusion or
other health-related issues. Incorporating ozone injection along with AS/VE would result in PCE destruction; however, it
complicates the system design, requires additional O&M (which can be significant due to the corrosive effects of ozone),
and adds to the capital cost. The continued need for recovering the vapor would be assessed over the life cycle of the
remediation.
Designing an AS/VE system will require that the vertical and cross-sectional profile of the PCE plume be well defined for
optimum placement of the air sparge points. Pilot testing is conducted to determine the “effective” radius of influence
of a sparge point and to define the initial and design operational parameters (i.e., number of sparge points, operating
pressures and flow rates, etc.). Testing of soil-gas permeability should be performed to design a VE system that will
capture the vapors created by the sparging action.
In Situ Chemical Oxidation with Directed Recirculation
Although the ISCO pilot testing conducted on the east side of the Mall property appeared to result in displacement of
contaminated groundwater into previously clean areas or zones, that testing did not incorporate extraction or
recirculation wells. Theoretically, extraction of a volume of groundwater equal to the volume of injectate should
minimize the amount of displacement of contaminated groundwater.
Short-term effectiveness of potassium permanganate has been demonstrated by laboratory testing and longevity of
permanganate has been shown by the pilot testing, suggesting that long-term effectiveness may be achievable.
Implementation and cost for this type of technology have not been thoroughly evaluated.
Summary of Preferred Alternative
Based on information currently available, the NDEP believes the Preferred Alternative meets the threshold criteria and
provides the best balance of tradeoffs among the other alternatives with respect to the balancing and modifying criteria.
The NDEP expects the Preferred Alternative to satisfy the following statutory requirements of CERCLA §121(b): 1) be
protective of human health and the environment; 2) comply with site action levels; 3) be cost-effective; 4) employ
permanent solutions and alternative treatment technologies or resource recovery technologies to the maximum extent
practicable; and 5) satisfy the preference for treatment as a principal element.
The Cleanup Process used by the USEPA follows a series of steps and documents, as outlined at:
http://www.epa.gov/superfund/cleanup/ Additional information on the USEPA process can be found at:
http://www2.epa.gov/cleanups The cleanup process followed by the NDEP is consistent with and similar to the USEPA process.
Proposed Plan for the Maryland Square PCE Site
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Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 19 of 20
IX.
COMMUNITY PARTICIPATION
The Proposed Plan is a document used to facilitate public involvement in the remedy selection process. The document
presents the lead agency’s Preferred Alternative to address contamination at the site, presents alternatives that were
evaluated, and explains the reasons the lead agency recommends the Preferred Alternative.
Comments on this Proposed Plan will be accepted by mail, e-mail or fax throughout the 60-day comment period, from
August 1, 2014 to October 1, 2014. Comments will be addressed in the “Responsiveness Summary,” which is included in
the Record of Decision (ROD). The final decision regarding the selected remedy is documented in the ROD after the lead
agency has considered all comments from both the support agency and the public.
Document Locations
Bureau of Corrective Actions
NDEP
901 S. Stewart St, Suite 4001
Carson City, NV 89701
Phone (775) 687-4670
Bureau of Corrective Actions
NDEP
2030 E. Flamingo Rd, Suite 230
Las Vegas, NV 89119
Phone: (702) 486-2850
NDEP Website Link
View the Proposed Plan, Administrative Record, and additional details and information for the Maryland Square PCE Site
at http://ndep.nv.gov/pce/maryland_square.htm
Public Meeting
Text needed describing location, time, format
Proposed Plan for the Maryland Square PCE Site
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Case 2:08-cv-01618-RCJ-GWF Document 1047-1 Filed 07/18/14 Page 20 of 20
Table 1. Comparative Analysis of Alternatives
Alternative 1
Comparison Criteria
No Further Action
Alternative
Alternative 2
Alternative 3
Alternative 4
Alternative 5
Groundwater Extraction and
Treatment (P&T) in East Parking Lot,
Permeable Reactive
In Situ Chemical
Biologically Enhanced In Situ
with Air Sparging and Soil Vapor
Barrier (PRB) using Zero- Oxidation (ISCO) of the
Treatment (ISB)
Extraction (AS/SVE) or ISCO with
Valent Iron (ZVI)
Entire Plume
Recirculation Wells in West Parking
Lot
Comparative Analysis Summary
Threshold Criteria
1) Overall Protection of Human
Health and the Envrionment
2) Achieving Action Levels*
Fails
Fails
Likely Meets
Likely Fails
Likely Fails
Likely Fails
Likely Meets
Likely Fails
Meets
Enhanced Bioremediation (Alt 2) is not compatible with site geochemistry. A PRB using ZVI (Alt 3) would be extremely difficult to
implement to 80 ft bgs, as well as being subject to passivation due to groundwater geochemistry. ISCO (Alt 4) appears to destroy PCE,
but migration is uncontrolled and displacement of contamination is a concern, along with safety issues. P&T (Alt 5) is believed to be the
safest option next to homes, with ISCO and AS/VE retained for the western parking lot on mall property.
Meets
Enhanced Bioremediation (Alt 2) and a PRB with ZVI (Alt 3) depend on reducing conditions and are not likely to perform successfully
over the long term, so these remedies are not expected to achieve or maintain action levels. The performance of ISCO (Alt 4) is
unknown because of the difficulty distinguishing between contaminant destruction and displacement of contaminated groundwater.
ISCO with Recirculation and AS/VE in the western mall parking lot in concert with P&T (Alt 5) is likely to acheive action levels in a timely
fashion.
4
Enhanced Bioremediation (Alt 2) and a PRB using ZVI (Alt 3) are expected to have low long-term effectivness due to incompatibility with
site geochemistry and the likely difficulty in maintaining reducing conditions. The long-term effectiveness of ISCO (Alt 4) is unknown
because of the difficulting discerning between efficacy and displacement. P&T in east parking lot, combined with AS/VE and ISCO with
Recirculation in the west parking lot (Alt 5), should remain effective over the long-term.
4
Enhanced Bioremediation (Alt 2) and a PRB using ZVI (Alt 3) are expected to produce only a small decrease in contaminant volume, and
may increase toxicity by production of more-toxic daughter products as a result of incomplete reductive dechlorination of PCE. ISCO
remedies (Alt 4) may decrease volume and toxicity, but without active recirculation wells may increase mobility by displacing the
contamination into previously clean area or depths. P&T, AS/VE, ISCO with Recirculation (Alt 5) should reduce mobility, toxicity and
volume of contaminants
3
Short-term effectiveness evaluates the degree of disruption caused by remedy implementation, as well as the rapidity of achieving
remediation goals. Enhanced Bioremediation (Alt 2) on Mall property would likely have minimal short-term disruption to the residential
neighborhood, but may be slow in effectiveness. A PRB using ZVI (Alt 3) would have moderate negative short-term impact during
construction and moderate to low effectiveness in the short term. ISCO on Mall property would have a low to moderate short-term
impact, depending on the oxidant used; however, ISCO throughout the plume (Alt 4) would have a high negative impact on the
neighborhood. P&T in the east parking lot, along with AS/VE and ISCO with Recirculation in the west parking lot (Alt 5) would likely have
moderate negative short-term impact during construction and optimization, but hydraulic containment with reinjection of clean water
may provide the fastest short-term effectiveness to achieve remediation goals in the neighborhood.
Primary Balancing Criteria
3) Long-Term Effectiveness
4) Reduction of Toxicity, Mobility
and Volume
5) Short-Term Impact
0
0
0
2
3
2
1
2
1
3
1
0
6) Implementability
0
3
1
0
3
7) Cost
0
4
3
1
2
Implementing Enhanced Bioremediation (Alt 2) is theoretically easy but acheiving reducing conditions may be difficult. Installing a ZVI
PRB (Alt 3) to 80 ft bgs would be difficult to highly impracticable. Implementing ISCO across the entire plume (Alt 4) would be relatively
easy on mall property but difficult in the neighborhood due to necessity of drilling hundreds of injection points. Installing a series of
P&T wells on the east side of mall property, along with AS/VE and ISCO with Recirculation on the west side of mall property(Alt 5)
should be easy to implement, though optimal placement of screens would require more detailed characterization of lithology in the
treatment areas.
Costs for all alternatives are estimated. The highest costs are likely to be for a ZVI PRB (Alt 3), ISCO throughout the plume (Alt 4), and
P&T with AS/VE and ISCO with Recirculation (Alt 5).
Modifying Criterion
Dependent on feedback from community members and other stakeholders
8) Community Acceptance
Note: The action level for PCE in groundwater under the residential neighborhood, (100 µg/L) protective of indoor air is 20 times higher than the MCL (5 µg/L); the action level for PCE (9.4 µg/m3) and TCE (6 µg/m3) in indoor air reflect the latest risk information from the USEPA.
Worst Option
TOTALS =
0
Proposed Plan for the Maryland Square PCE Site
Best Option
14
8
5
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